Diluent

A diluent (also referred to as a filler, dilutant or thinner) is a diluting agent. Certain fluids are too viscous to be pumped easily or too dense to flow from one particular point to the other. This can be troublesome, because it might not be economically feasible to transport such fluids in this state. To ease this restricted movement, diluents are added. This decreases the viscosity of the fluids, thereby also decreasing the pumping/transportation costs.

One industrial application is the transport of crude oil via pipelines. Heavy crude oil/bitumen are fluids with high viscosity, especially at low temperatures. The addition of a diluent enables the diluted fluid (dilbit in the case of bitumen) to meet pipeline specifications in order for it to be efficiently transported. Typical diluent in this case is naphtha or condensate.[1]

Types of diluents more familiar to the general public include paint thinner and nail polish thinner, both of which improve the consistency and applicability of the products to which they are added. Diluent is also used as a term in solvent extraction for an inert solvent in which a metal extraction agent (extractant) is dissolved. In solvent extraction the diluent has potentially several uses. It can be used as a solvent (in the purely chemical sense rather than the solvent extraction sense) to dissolve an extractant which is a solid and so render it suitable for use in a liquid–liquid extraction process. In other cases such as PUREX nuclear reprocessing the diluent (kerosene) is used to reduce the maximum metal loading which the organic layer can reach. If the organic layer was to acquire too much metal then a solid metal complex might form, or more worryingly in a nuclear process the potential for a criticality accident if the fissile metal concentration in the organic phase becomes too high. Commonly in both lab and industrial solvent extraction of metals petroleum kerosene is used as a diluent, but in recent times it has been shown that Neste's second generation biodiesel which was formed by hydrodeoxygenation can be used as a diluent.[2]

Water is probably the most common and familiar diluent, but many substances, such as oils, do not dissolve well in water and therefore require different diluents to be diluted effectively without separating into parts.

  1. ^ Aoyama, Tomoki; Kayukawa, Tomoki; Fujimoto, Takayoshi (2018). Technology Division, Technology Innovation Center (ed.). "SCWC Process, Result of Pilot Plant Testing in Canada and Scaling Up to Commercia Unit" (pdf). 日揮技術ジャーナル (in Japanese). 6 (5). JGC Corporation: 3. Retrieved 2021-04-24.
  2. ^ https://pubs.rsc.org/en/content/articlelanding/2024/su/d3su00078h#!divCitation https://doi.org/10.1039/D3SU00078H Mark R. StJ. Foreman, Richard K. Johansson, Gloria Mariotti, Ingmar Persson, Behabitu E. Tebikachew and Mikhail S. Tyumentsev, RSC Sustainability 2024